Henrik Ottosson

Publications

Selection of publications

• Is Excited-State Aromaticity a Driving Force for Planarization of Dibenzannelated 8 Π-Electron Heterocycles? (2019)
• Excited-state proton transfer relieves antiaromaticity in molecules (2019)
• Triplet state homoaromaticity (2018)
• Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives (2017)
• Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene (2016)
• The Missing C-1-C-5 Cycloaromatization Reaction (2015)
• Excited State Aromaticity and Antiaromaticity (2014)
• ORGANIC PHOTOCHEMISTRY Exciting excited-state aromaticity (2012)

Recent publications

• Light-driven (cross-)dimerization of terpenes as a route to renewable C₁₅-C₃₀ crudes for fuel and lubricant oil applications (2023)
• Excited-State (Anti)Aromaticity Explains Why Azulene Disobeys Kasha's Rule (2023)
• In the quest of Huckel-Huckel and Huckel-Baird double aromatic tropylium (tri)cation and anion derivatives (2023)
• A focus on aromaticity (2023)
• Excited-state aromaticity and antiaromaticity special issue (2023)

All publications

Articles

• Light-driven (cross-)dimerization of terpenes as a route to renewable C₁₅-C₃₀ crudes for fuel and lubricant oil applications (2023)
• Excited-State (Anti)Aromaticity Explains Why Azulene Disobeys Kasha's Rule (2023)
• In the quest of Huckel-Huckel and Huckel-Baird double aromatic tropylium (tri)cation and anion derivatives (2023)
• A focus on aromaticity (2023)
• Excited-state aromaticity and antiaromaticity special issue (2023)
• Single-Not Double-3D-Aromaticity in an Oxidized Closo Icosahedral Dodecaiodo-Dodecaborate Cluster (2023)
• Azaboracyclooctatetraenes reveal that the different aspects of triplet state Baird-aromaticity are nothing but different (2023)
• Toward combined photobiological-photochemical formation of kerosene-type biofuels (2023)
• Photochemistry Driven by Excited-State Aromaticity Gain or Antiaromaticity Relief (2023)
• Three-Dimensional Fully π-Conjugated Macrocycles (2022)
• A combined photobiological-photochemical route to C10 cycloalkane jet fuels from carbon dioxide via isoprene (2022)
• Triplet State Baird Aromaticity in Macrocycles (2021)
• Guidelines for Tuning the Excited State Huckel-Baird Hybrid Aromatic Character of Pro-Aromatic Quinoidal Compounds** (2021)
• Inside Cover (2021)
• Excited state character of Cibalackrot-type compounds interpreted in terms of Hückel-aromaticity (2021)
• Strategies for Design of Potential Singlet Fission Chromophores Utilizing a Combination of Ground-State and Excited-State Aromaticity Rules (2020)
• Nanomolecular electronic devices based on AuNP molecule nanoelectrodes using molecular place-exchange process (2020)
• Degradation of Pharmaceuticals through Sequential Photon Absorption and Photoionization in Amiloride Derivatives (2020)
• Electron-driven proton transfer relieves excited-state antiaromaticity in photoexcited DNA base pairs (2020)
• Structure–Property Relationships in Unsymmetric Bis(antiaromatics) (2020)
• Tuning the Baird aromatic triplet-state energy of cyclooctatetraene to maximize the self-healing mechanism in organic fluorophores (2020)
• Impact of Excited-State Antiaromaticity Relief in a Fundamental Benzene Photoreaction Leading to Substituted Bicyclo[3.1.0]hexenes (2020)
• Is Excited-State Aromaticity a Driving Force for Planarization of Dibenzannelated 8 Π-Electron Heterocycles? (2019)
• Excited-state proton transfer relieves antiaromaticity in molecules (2019)
• Exploiting the Aromatic Chameleon Character of Fulvenes for Computational Design of Baird-Aromatic Triplet Ground State Compounds (2019)
• Torsional Bias as a Strategy To Tune Single-triplet Gaps in Organic Diradicals (2018)
• Norbornadiene-quadricyclane photochromic systems for solar energy storage applications and testing in devices (2018)
• Triplet state homoaromaticity (2018)
• Superior adhesion of graphene nanoscrolls (2018)
• Substituent Effects in Chain-Breaking Aryltellurophenol Antioxidants (2018)
• Can Baird's and Clar's Rules Combined Explain Triplet State Energies of Polycyclic Conjugated Hydrocarbons with Fused 4n pi- and (4n+2)pi-Rings? (2017)
• Can Baird’s and Clar’s Rules Combined Explain Triplet State Energies of Polycyclic Conjugated Hydrocarbons with Fused 4nπ- and (4n + 2)π-Rings? (2017)
• The Silacyclobutene Ring (2017)
• Cyclopropyl Group (2017)
• A Computational Investigation of the Substituent Effects on Geometric, Electronic, and Optical Properties of Siloles and 1,4-Disilacyclohexa-2,5-dienes (2017)
• Unraveling factors leading to efficient norbornadiene-quadricyclane molecular solar-thermal energy storage systems (2017)
• White-light photoassisted covalent functionalization of graphene using 2-propanol (2017)
• Benzo[b]thiophene Fusion Enhances Local Borepin Aromaticity in Polycyclic Heteroaromatic Compounds (2017)
• Unraveling Excited-Singlet-State Aromaticity via Vibrational Analysis (2017)
• Energetics of Baird aromaticity supported by inversion of photoexcited chiral [4n]annulene derivatives (2017)
• Expanding the (Cross-)Hyperconjugation of 1,4-Disilacyclohexa-2,5-dienes to Larger Monomers and Oligomers (2016)
• Analysis of a Compound Class with Triplet States Stabilized by Potentially Baird Aromatic [10]Annulenyl Dicationic Rings (2016)
• Many-body effects and excitonic features in 2D biphenylene carbon (2016)
• Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene (2016)
• Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene (2016)
• Diindeno-fusion of an anthracene as a design strategy for stable organic biradicals (2016)
• Polyfulvenes (2015)
• The 6,6-Dicyanopentafulvene Core (2015)
• Nano-fabrication of molecular electronic junctions by targeted modification of metal-molecule bonds (2015)
• The Missing C-1-C-5 Cycloaromatization Reaction (2015)
• Cooperative Gold Nanoparticle Stabilization by Acetylenic Phosphaalkenes (2015)
• AROMATICITY A light-switched yin and yang pair (2015)
• The excited state antiaromatic benzene ring (2015)
• The first intramolecular silene Diels-Alder reactions (2014)
• Optimization of the Cyclic Cross-Hyperconjugation in 1,4-Ditetrelcyclohexa-2,5-dienes (2014)
• Configuration- and Conformation-Dependent Electronic Structure Variations in 1,4-Disubstituted Cyclohexanes Enabled by a Carbon-to-Silicon Exchange (2014)
• In Search of Flexible Molecular Wires with Near Conformer-Independent Conjugation and Conductance (2014)
• Stability optimisation of molecular electronic devices based on nanoelectrode-nanoparticle bridge platform in air and different storage liquids (2014)
• Siloles and cyclopentadienes as "aromatic chameleons" influenced by aromaticity in both the ground state and lowest electronically excited states (2014)
• Impact of Ground- and Excited-State Aromaticity on Cyclopentadiene and Silole Excitation Energies and Excited-State Polarities (2014)
• A computational study of potential molecular switches that exploit Baird's rule on excited-state aromaticity and antiaromaticity (2014)
• Excited State Aromaticity and Antiaromaticity (2014)
• 1,4-Disilacyclohexa-2,5-diene (2014)
• Computational Investigation of Brook-Type Silabenzenes and Their Possible Formation through [1,3]-Si -> O Silyl Shifts (2013)
• Strong neutral cross-hyperconjugation and linear hyperconjugation enabled by saturated Group 14 element E(E ' R-3)(2), (E ' R-3)E-E(E ' R-3), and E(E ' R-2)(2)E segments (2013)
• Cross-hyperconjugation (2013)
• Charge transfer through cross-hyperconjugated versus cross-pi-conjugated bridges (2013)
• Identification of vibrational signatures from short chains of interlinked molecule-nanoparticle junctions obtained by inelastic electron tunnelling spectroscopy (2013)
• Organic Single Molecular Structures for Light Induced Spin-Pump Devices (2013)
• Use of two-dimensional photoelectron spectroscopy in the decomposition of an inner-shell excitation spectrum broadened by super-Coster-Kronig decay (2013)
• Conductance through Carbosilane Cage Compounds (2013)
• New Class of Molecular Conductance Switches Based on the [1,3]-Silyl Migration from Silanes to Silenes (2013)
• Efficient and convenient acid catalyzed hypersilyl protection of alcohols and thiols by tris(trimethylsilyl)silyl-N,N-dimethylmethaneamide (2013)
• Coupling of Disilane and Trisilane Segments Through Zero, One, Two, and Three Disilanyl Bridges in Cyclic and Bicyclic Saturated Carbosilanes (2013)
• Aromaticity Effects on the Profiles of the Lowest Triplet-State Potential-Energy Surfaces for Rotation about the CC Bonds of Olefins with Five-Membered Ring Substituents (2013)
• Baird's rule on excited state (anti)aromaticity as a tool for rationalization of photophysical and photochemical properties and processes (2013)
• Highly Efficient and Convenient Acid Catalyzed Hypersilyl Protection of Alcohols and Thiols by Tris(trimethylsilyl)silyl-N,N-dimethylmethaneamide (2012)
• Silaphenolates and Silaphenylthiolates (2012)
• Exploration of the π-Electronic Structure of Singlet, Triplet, and Quintet States of Fulvenes and Fulvalenes Using the Electron Localization Function (2012)
• ORGANIC PHOTOCHEMISTRY Exciting excited-state aromaticity (2012)
• Silene equivalents through the rhodium-catalysed reactions of alpha-hypersilyl diazoesters (2011)
• Control of junction resistances in molecular electronic devices fabricated by FIB (2011)
• Multidecker Bis(benzene)chromium (2011)
• Influence of excited state aromaticity in the lowest excited singlet states of fulvene derivatives (2011)
• Formation and NMR Spectroscopy of ω-Thiol Protected α,ω-Alkanedithiol Coated Gold Nanoparticles and Their Usage in Molecular Charge Transport Junctions (2011)
• Interpolation of Atomically Thin Hexagonal Boron Nitride and Graphene (2011)
• Substituent Effects on the Electron Affinities and Ionization Energies of Tria-, Penta-, and Heptafulvenes (2010)
• Unsuccessful attempts to add alcohols to transient 2-amino-2-siloxy- silenes - leading to a new benign route for base-free alcohol protection (2010)
• Effects of the silicon core structures on the hole mobility of star-shaped oligothiophenes (2010)
• Formation of Acylsilenolates from Bis(acyl)trisilanes as the Silicon Analogues of Acylenolates (2010)
• Proton and Hydride Affinities in Excited States (2010)
• Near sulfur L-edge X-ray absorption spectra of methanethiol in isolation and adsorbed on a Au(111) surface (2010)
• On the Importance of Clar Structures of Polybenzenoid Hydrocarbons as Revealed by the n-Contribution to the Electron Localization Function (2010)
• Effects of Substituents and Counterions on the Structures of Silenolates (2009)
• Aromaticity Changes along the Lowest-Triplet-State Path for C=C Bond Rotation of Annulenyl-Substituted Olefins Probed by the Electron Localization Function (2009)
• Relation between the π-Contribution to Reversed Si═C Bond Polarization and the Reaction Profile for the Thermolytic Formation of Silenes (2008)
• Relation between the pi-Contribution to Reversed Si=C Bond Polarization and the Reaction Profile for the Thermolytic Formation of Silenes (2008)
• Silenes (2008)
• Triplet-state aromaticity of 4n pi-electron monocycles (2008)
• Characterization of the Chemisorption of Methylsilane on a Au(1,1,1) Surface from the Silicon K- and L-Edge Spectra (2007)
• A Computational Investigation of the Retrocyclization Reaction of Silacyclo-but-2-enes to 1-silabuta-1,3-dienes (2007)
• Scope and Limitations of Baird's Theory on Triplet State Aromaticity (2007)
• Silylenes, Silenes, and Disilenes: Novel Silicon-Based Reagents for Organic Synthesis? (2006)
• Design principles for a-tocopherol analogues (2006)
• Substituent Effects on the Basicity of 3,7-Diazabicyclo[3.3.1]nonanes (2006)
• J. Org. Chem. (2005)
• Heavy Group 14 1,(n+2)-Dimetallabicyclo[n.n.n]alkanes and 1.(n+2)-Dimetalla[n.n.n]propellanes: Are They All Realistic Synthetic Targets? (2005)
• In search of 1,3-disila/germa/stannabicyclo[1.1.1]pentanes with short bridgehead-bridgehead distances and low ring strain energies (2005)
• An improved pathway to 6,6-disubstituted fulvenes (2004)
• Fulvenes, Fulvalenes, and Azulene: Are They Aromatic Chameleons? (2004)
• On the origin of cis selectivity in the cyclization of N-protected 2-substituted 3-aza-5-hexenyl radicals (2004)

Chapters

• Case Uppsala, Campus Polacksbacken:  Location, surrounding, stakeholders (2017)

Conferences

• A 10-nm sized few molecule portable platform to assess molecular electronics properties (2015)
• Use of a nanoelectrode nanoparticle bridge platform in molecular electronics (2010)